(R)-(+)-1-Butyn-3-Ol (R)-(+)-3-丁炔-2-醇

CAS 42969-65-3 MFCD00211237

化学结构图

42969-65-3
SMILES: C#C[C@@H](C)O

化学属性

Mol. FormulaHC≡CCH(OH)CH3
Mol. Weight70
Refractive index1.4240 to 1.4280
Boiling Point108-111
Density0.89
Flash Point26°C(lit.)
TSCANo
Appearance 该品无色至淡黄色液体。相对密度0.894-0.895。

别名和识别编码

Chemical Name(R)-(+)-1-Butyn-3-Ol
CAS Number42969-65-3
PubChem Substance ID87558985
MDL NumberMFCD00211237
Beilstein Registry Number3587272
Synonym (1R)-1-Methyl-2-propyne-1-ol (2R)-But-3-yn-2-ol (R)-(+)-1-BUTYN-3-OL (R)-(+)-3-BUTYN-2-OL (R)-(+)-3-Butyn-2-ol, 98%, ee:98% (R)-(+)-3-丁炔-2-醇 (R)-3-BUTYN-2-OL (R)-3-BUTYNE-2-OL (R)-but-3-yn-2-ol (±)-3-丁炔-2-醇 (±)3-丁炔-2-醇 -(+)-1-Butyn-3-ol 1-Butyn-3-ol (55% in water) 1-Ethynylethanol 1-Methyl-2-propynyl alcohol 1-Methylpropargyl 1-丁炔-3-醇 3-BUTYN-2-OL 98% 3-BUTYN-2-OL (55% SOLUTION IN WATER) ABOUT 55% 3-BUTYN-2-OL SOLUTION, ~55% IN WATER 3-butyn-2-0l 3-butyn-2-olsolution 3-丁炔-2-醇 ?-(+)-3-硫酸丁基卡因-2-醇 HCequivCCH(CH3)OH alpha-Methylpropargyl alcohol r-3-butyn-2-ol98%
EC Number217-978-1
Chemical Name Translation(R)-(+)-3-丁炔-2-醇
Reaxys-RN3587272
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分类

  • {SNA} Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks

相关文献及参考

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 6.1 F,T+ T+ T,F
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H300 Fatal if swallowed 吞食致命
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H330 Fatal if inhaled 吸入致命
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P310+P330
  • P302+P352+P310+P361+P364
  • P303+P361+P353
  • P304+P340+P310
  • P305+P351+
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P337+P313
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2929
Risk Statements
  • R10 Flammable 易燃
  • R11 Highly flammable 非常易燃
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R28 Very toxic if swallowed 吞咽极毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Hazard Class6.1/3
Storage condition Flammables area Poison room
RTECSES0709800

其他信息

  • 储运特性:库房通风低温干燥; 与氧化剂分开存放; 不宜久储, 以防聚合
  • MOL 文件:2028-63-9.mol
  • Hazard Note:Irritant
  • F:10
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • MOL 文件:42969-65-3.mol
  • MSDS 信息:(R)-(+)-3-Butyn-2-ol(42969-65-3).msds
  • 毒性分级:剧毒
  • 3-丁炔-2-醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0750 3-丁炔-2-醇(55%的水溶液,约7.5mol/L) 3-Butyn-2-ol (55% in Water, ca. 7.5mol/L) 500ML 2930元 2014/06/02 B0750 3-丁炔-2-醇(55%的水溶液,约7.5mol/L) 3-Butyn-2-ol (55% in Water, ca. 7.5mol/L) 25ML 360元 2014/06/02 B1001 3-丁炔-2-醇 3-Butyn-2-ol 25ML 772元
  • Sigma Aldrich:42969-65-3(sigmaaldrich)
  • 急性毒性:口服- 小鼠 LD50: 30 毫克/ 公斤
  • 类别:易燃液体
  • 图谱信息:3-丁炔-2-醇(2028-63-9)核磁图( 1 HNMR) 3-丁炔-2-醇(2028-63-9)质谱(MS) 3-丁炔-2-醇(2028-63-9)红外图谱(IR1) 3-丁炔-2-醇(2028-63-9)核磁图( 13 CNMR)
  • Alfa Aesar:(±)-3-丁炔-2-醇,98% ()-3-Butyn-2-ol, 98%(2028-63-9)
  • Sigma Aldrich:2028-63-9(sigmaaldrich)
  • Acros Organics:3-Butyn-2-ol, 97%(2028-63-9)
  • Acros Organics:(R)-(+)-3-丁炔-2-醇 (R)-(+)-3-Butyn-2-ol, 98% ee, 98%(42969-65-3)
  • 比旋光度:46.7 ° (neat)
  • (R)-(+)-3-丁炔-2-醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2909 (R)-(+)-3-丁炔-2-醇 (R)-(+)-3-Butyn-2-ol 1G 990元 2010/06/21 366300050 (R)-(+)-3-丁炔-2-醇 (R)-(+)-3-Butyn-2-ol 98%, 98% ee 5 GR 7187元 2010/06/21 366300010 (R)-(+)-3-丁炔-2-醇 (R)-(+)-3-Butyn-2-ol 98%, 98% ee 1 GR 1627元
  • TCI Shanghai:(R)-(+)-3-丁炔-2-醇 (R)-(+)-3-Butyn-2-ol,>;98.0%(GC)(42969-65-3)
  • 可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生刺激烟雾
  • TCI Shanghai:3-丁炔-2-醇(55%的水溶液,约7.5mol/L) 3-Butyn-2-ol (55% in Water, ca. 7.5mol/L)(2028-63-9)
  • Alfa Aesar:(R)-(+)-3-丁炔-2-醇,99% (R)-(+)-3-Butyn-2-ol, 99%(42969-65-3)

系列性分类


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