Bis(1,5-Cyclooctadiene)Dimethoxydiiridium 甲氧基(环辛二烯)合铱二聚体

CAS 12148-71-9 MFCD08459360

化学结构图

12148-71-9
SMILES: C1=CCCC=CCC1.C1=CCCC=CCC1.C[O+]1[Ir-]2[O+](C)[Ir-]12

化学属性

Mol. FormulaC18H30Ir2O2
Mol. Weight662.86
TSCANo
Melting Point154-177°C
Stability对光、空气和湿度敏感

别名和识别编码

Chemical NameBis(1,5-Cyclooctadiene)Dimethoxydiiridium
Synonym [Ir(OMe)(1,5-cod)]2 {LY} [Ir(OMe)(1,5-cod)]2 {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Ir(OMe)(1,5-cod)]2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD08459360
CAS Number12148-71-9
PubChem Substance ID160871404
Reaxys-RN14520157
Chemical Name Translation甲氧基(环辛二烯)合铱二聚体
LabNetwork Molecule IDLN01745509
Canonical SMILESCO1[Ir]O(C)[Ir]1.C2=C\CC/C=C\CC/2.C3/C=C\CC/C=C\C3
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分类

  • {uni_hamburg}
  • {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Iridium
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium
  • {SNA} C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Development Quantities for Research, Iridium

相关文献及参考

  • Catalyst used in combination with a bipyridine derivative for aromatic C-H borylation of arenes and heteroarenes with Pinacolborane, L17558: Chem. Commun., 2924 (2003).
  • Short: III/10b

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition -20°C, protect from light, stored under nitrogen {LY} -20°C, protect from light, stored under nitrogen 0-10°C 2-8°C, protect from light, stored under nitrogen <0°C Light, Air & Moisture Sensitive {} {LY} -20°C, protect from light, stored under nitrogen {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect
GHS Symbol
WGK Germany3
Precautionary statements
  • P337+P313
  • P304+P340+P312
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi

系列性分类


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