Methanol-D4 氘代甲醇-D4

CAS 811-98-3 MFCD00044637

化学结构图

811-98-3
SMILES: [2H]OC([2H])([2H])[2H]

化学属性

Mol. FormulaC4H9D4OSi
Mol. Weight109.26
Density0.888
Refractive indexn20/D 1.326(lit.)
Boiling Point65
Flash Point11°C(lit.)
TSCAYes
Melting Point-99
Stability对光和湿度敏感
Danger-Level甲类

别名和识别编码

Chemical NameMethanol-D4
MDL NumberMFCD00044637
CAS Number811-98-3
EC Number212-378-6
Beilstein Registry Number1733278
Synonym Methanol-d4(TMS) {Chemicalbook} METHYL-D3 ALCOHOL-D, 100.0 ATOM % D METHYL-D3 ALCOHOL-D, 99.8+ ATOM % D (CON TAINS 1% V/V TMS) Methanol-D Methyl Alcohol-d4 Methyl Alcohol-d4, Tetradeuteromethanol Perdeuteromethanol methanol-d3alcohol-d {} {Chemicalbook} METHYL-12C-D3 ALCOHOL-D {} {} {Chemicalbook} METHYL ALCOHOL-D4 {} {} {} {Chemicalbook} METHANOL-D4, 99.8 + ATOM % D (1PK=10 X 1ML) {} {} {} {} {Chemicalbook} METHANOL-D4, 100.0 ATOM % D (1PK=10 X 0.25ML) {} {} {} {} {} {Chemicalbook} METHANOL-D4 , 99.8 + ATOM % D (1PK=5 X 0.5ML) {} {} {} {} {} {} {Chemicalbook} Deuterated methanol {} {} {} {} {} {} {} {Chemicalbook} CD3OD {} {} {} {} {} {} {} {} {Chemicalbook} 4 全氘代甲醇 四氘代甲醇 四氘代甲醇 氘代甲醇 氘代甲醇, 99.8%(ISOTOPIC), CONTAINS 0.05% V/V TMS 氘代甲醇,含TMS 氘代甲醇-D{4}, 100%(ISOTOPIC) 氘代甲醇-D{4},
PubChem Substance ID87560228
Alfabeta NameMETHANOL D4-
Chemical Name Translation氘代甲醇-D4
Reaxys-RN1733278
InChIInChI=1S/CH4O/c1-2/h2H,1H3/i1D3,2D
LabNetwork Molecule IDLN00163702
Canonical SMILESC[Si](C)C.[2H]OC([2H])([2H])[2H]
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分类

  • {SNA} Alphabetical Listings, M, Methanol-d4, NMR Solvents, NMR Solvents and Reagents, Solvent by Application, Solvents, Spectroscopy Solvents (IR, NMR, UV/Vis), Stable Isotopes
  • {SNA} Alphabetical Listings, M, Methanol-d4,
  • {SNA} Anhydrous NMR Solvents, Methanol-d4,

相关文献及参考

  • Beilstein:1(4)1244

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S7 Keep container tightly closed 保存在严格密闭容器中;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R23/34/35
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P303+P361+P353
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P307+P311
  • P308+P311
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P337+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H370 Causes damage to organs 导致器官损伤
Packing GroupII
UN Number 1230 UN 1230 3/PG 2 UN1230
Warnings IRRITANT
Hazard Codes 3 F,T
Hazard Class3/6.1
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {Chemicalbook} Flammables area 储存温度2-8℃,充氩保存 避光防潮,室温保存,充氩储存 避光防潮,室温保存.
RTECSPC1400000

其他信息

  • TCI Shanghai:氘代甲醇-d4 99.0原子%D Methanol-d4 99.8atom%D(811-98-3)
  • Acros Organics:氘代甲醇 Methanol-d4, packaged in 0.75 ml ampules, 100.0 atom % D, for NMR(811-98-3)
  • 氘代甲醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80042061 氘代甲醇 D4 10x0.5ml(盒) 398元 2011/04/16 M1869 氘代甲醇-d4 99.0原子%D Methanol-d4 99.8atom%D 10G 900元 2010/06/21 329920500 氘代甲醇 Methanol-d4 , for NMR, contains 0.03 v/v% TMS, 99.8 atom % D 50 ML 4766元
  • MOL 文件:811-98-3.mol
  • Sigma Aldrich:811-98-3(sigmaaldrich)
  • 存储注意事项:氮气保护
  • F:10-21
  • Alfa Aesar:4 , 99.8%(Isotopic)(811-98-3)" href="http://www.alfa.com/zh/GP100w.pgm?DSSTK=36501&CAS;=811-98-3">氘代甲醇-d{4},99.8%(Isotopic) Methanol-d 4 , 99.8%(Isotopic)(811-98-3)
  • 图谱信息:氘代甲醇(811-98-3)核磁图( 13 CNMR) 氘代甲醇(811-98-3)红外图谱(IR1) 氘代甲醇(811-98-3)核磁图( 1 HNMR) 氘代甲醇(811-98-3)质谱(MS)

系列性分类


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