1-(Bromomethyl)-2,3,4,5,6-Pentafluorobenzene 2,3,4,5,6-五氟溴化苄

CAS 1765-40-8 MFCD00000299

化学结构图

1765-40-8
SMILES: Fc1c(F)c(F)c(CBr)c(F)c1F

化学属性

Mol. FormulaC7H2BrF5
Mol. Weight260.99
Boiling Point176°C
Melting Point19-20
Refractive index1.4700 to 1.4730
Density1.728
Flash Point83°C(lit.)
TSCANo
Appearance colorless liq.

别名和识别编码

Chemical Name1-(Bromomethyl)-2,3,4,5,6-Pentafluorobenzene
CAS Number1765-40-8
Alfabeta NamePENTAFLUOROBENZYLBROMIDE 23456-,,,,
MDL NumberMFCD00000299
Synonym α-溴-2,3,4,5,6-五氟甲苯 (溴甲基)五氟苯 1-(Bromomethyl)-2,3,4,5,6-pentafluorobenzene 1-Bromomethylpentafluorobenzene 2 2,3,4,5,6 -五氟苄溴 2,3,4,5,6-PENTAFLUOROBENZYL BROMIDE 99% 2,3,4,5,6-Pentafluorobenzyl bromide, (Bromomethyl)pentafluorobenzene 2,3,4,5,6-Pentafluorobenzyl bromide, 98+% 2,3,4,5,6-PentafluorobenzylBrimide 2,3,4,5,6-五氟溴化苄 2,3,4,5,6-五氟溴苄 2,3,4,5,6-五氟苄基溴 2,3,4,5,6-五氟苯甲基溴, 98+% 2,3,4,5,6-五氟苯甲基溴, 99+% Benzene, (bromomethyl)pentafluoro- PFBBR Pentafluorobenzylbromide,98+% à-bromo-2,3,4,5,6-pentafluorotoluene α-溴-2,3,4,5,6-四氟甲苯
PubChem Substance ID74484
EC Number217-182-4
Beilstein Registry Number647808
Reaxys-RN647808
Chemical Name Translation2,3,4,5,6-五氟溴化苄
InChIKeyXDEPVFFKOVDUNO-UHFFFAOYSA-N
LabNetwork Molecule IDLN00110900
InChIInChI=1S/C7H2BrF5/c8-1-2-3(9)5(11)7(13)6(12)4(2)10/h1H2
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分类

  • {SA} Analytical Reagents, Analytical/Chromatography, Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C7, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents GC, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated O
  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C7, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • Acylation Reagents,

产品应用

  • 衍生化试剂，用于气相色谱分析多功能硫醇。用于制备五氟苯酯。

相关文献及参考

  • Reagent for derivatization of alcohols, carboxylic acids, sulfonamides, etc. for GC: J. Chromat., 107, 327 (1975).

安全信息

Warnings IRRITANT, LACHRYMATOR, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C C,Xi
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 3265 UN 3265 8/PG 2 UN3265
Packing GroupII
Hazard Class8

其他信息

  • F:19
  • MOL 文件:1765-40-8.mol
  • 图谱信息:&-溴-2,3,4,5,6-五氟甲基苯酸酯(1765-40-8)质谱(MS) &-溴-2,3,4,5,6-五氟甲基苯酸酯(1765-40-8)红外图谱(IR1) &-溴-2,3,4,5,6-五氟甲基苯酸酯(1765-40-8)核磁图( 1 HNMR)
  • Hazard Note:Irritant/Lachrymatory
  • 用途一:衍生化试剂，用于气相色谱分析多功能硫醇。用于制备五氟苯酯。
  • &-溴-2,3,4,5,6-五氟甲基苯酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0809 五氟苄溴 Pentafluorobenzyl Bromide 1G 189元 2014/06/02 P0809 五氟苄溴 Pentafluorobenzyl Bromide 25G 1740元 2014/06/02 P0809 五氟苄溴 Pentafluorobenzyl Bromide 5G 532元
  • Acros Organics:五氟苄基溴 alpha-Bromo-2,3,4,5,6-pentafluorotoluene, 97%(1765-40-8)
  • Sigma Aldrich:1765-40-8(sigmaaldrich)
  • TCI Shanghai:五氟苄溴 Pentafluorobenzyl Bromide,>;98.0%(GC)(1765-40-8)
  • 上游原料:溴 --> 五氧化二磷 --> 2,3,4,5,6-五氟甲苯
  • Alfa Aesar:2,3,4,5,6-五氟苯甲基溴,98+% 2,3,4,5,6-Pentafluorobenzyl bromide, 98+%(1765-40-8)
  • 敏感性:Lachrymatory

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Alkylation & Esterification - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C7 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C7 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Alkylation Reagents - Derivatization Reagents
  5. General Alkylation Reagents - Alkylation Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C6
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents GC
  4. Reagents for Acylation
  1. Analytical & Chromatography 分析化学与色谱
  2. Gas Chromatography (GC) 气相色谱
  3. Derivatization Reagents
  4. Reagents for Acylation
  1. Organo Fluorine
  2. Fluorine

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