Methyl 3-Chloro-3-oxopropionate 丙二酸甲酯酰氯

CAS 37517-81-0 MFCD00013657

化学结构图

37517-81-0
SMILES: COC(=O)CC(=O)Cl

化学属性

Mol. FormulaC4
Mol. Weight137
Refractive index1.4310 to 1.4350
Boiling Point57-59
Density1.273
Flash Point80°C(lit.)
TSCANo

别名和识别编码

Chemical NameMethyl 3-Chloro-3-oxopropionate
Synonym Methyl 3-chloro-3-oxopropionateMalonic acid monomethyl ester chloride 3-Chloro-3-oxopropionic acid methyl ester Malonic acid monomethyl ester chloride~Methyl (chloroformyl)acetate (Chlorocarbonyl)acetic acid methyl ester 丙二酸甲酯酰氯 Propanoic acid, 3-chloro-3-oxo-, methyl ester Methyl 3-chloro-3-oxopropionate; Methyl chloroformylacetate
PubChem Substance ID160871398
EC Number253-540-6
Beilstein Registry Number1754078
MDL NumberMFCD00013657
CAS Number37517-81-0
Chemical Name Translation丙二酸甲酯酰氯
Reaxys-RN1754078
InChIKeyUTBCRHAMJFMIIR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00010065
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分类

  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Beilstein: 2,IV,1886

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P370+P378
  • P304+P340
  • P304+P340+P310
  • P403+P235
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P301+P330+P331
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
Signal word
Packing GroupII
UN Number UN3265 UN 3265 8/PG 2
Risk Statements
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R34 Causes burns 会导致灼伤
Safety Statements
Storage condition Moisture Sensitive 密封充氩保存 0-10°C 2-8°C
Hazard Codes C
Hazard Class8

其他信息

  • F:8-10-19
  • MSDS 信息:Methyl malonyl chloride(37517-81-0).msds
  • Sigma Aldrich:37517-81-0(sigmaaldrich)
  • 丙二酸甲酯酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 414510050 丙二酸甲酯酰氯 Methyl malonyl chloride 97% 5 GR 611元 2010/06/21 414511000 丙二酸甲酯酰氯 Methyl malonyl chloride 97% 100 GR 6287元 2010/06/21 414510250 丙二酸甲酯酰氯 Methyl malonyl chloride 97% 25 GR 1926元
  • MOL 文件:37517-81-0.mol
  • Acros Organics:甲基丙二酰氯 Methyl malonyl chloride, 97%(37517-81-0)
  • 敏感性:Lachrymatory
  • Alfa Aesar:甲基丙二酰氯,97% Methyl malonyl chloride, 97%(37517-81-0)
  • Hazard Note:Corrosive/Lachrymatory/Keep Cold

系列性分类