1-Bromo-3-Fluorobenzene 间溴氟苯

CAS 1073-06-9 MFCD00000326

化学结构图

1073-06-9
SMILES: Fc1cccc(Br)c1

化学属性

Mol. FormulaC6H4BrF
Mol. Weight175.00
Density1.567
Refractive index1.5250 to 1.5290
Boiling Point149-151°C at 760 mmHg
Flash Point46°C
TSCAYes
Melting Point-8 °C
Solubility不溶
Appearance 无色透明液体。熔点148-150℃，沸点：149℃-151℃。闪点：38℃，比重： 1.567，折光率：1.5260。
Stability对光线敏感
pH:A

别名和识别编码

Chemical Name1-Bromo-3-Fluorobenzene
Synonym 3-Bromofluorobenzene {LY} 3-Bromofluorobenzene {} {LY} 3-Bromofluorobenzene {} {} {LY} 3-Bromofluorobenzene {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {}
MDL NumberMFCD00000326
CAS Number1073-06-9
EC Number214-023-0
Beilstein Registry Number1853969
PubChem Substance ID14082
Reaxys-RN1853969
Chemical Name Translation间溴氟苯
InChIKeyQDFKKJYEIFBEFC-UHFFFAOYSA-N
Wiswesser Line NotationFR CE
LabNetwork Molecule IDLN00195149
InChIInChI=1S/C6H4BrF/c7-5-2-1-3-6(8)4-5/h1-4H
Canonical SMILESFC1=CC(Br)=CC=C1
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分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 医药、农药、液晶材料中间体。

相关文献及参考

  • Short: III/35D2
  • Short: III/20b
  • Lithiation with Li 2,2,6,6-tetramethylpiperidide (LTMP) at -75o occurs at the 2-position. The yield of 2-bromo-6-fluorobenzoic acid obtained after carboxylation can be increased to 93% by the use of a base consisting of a 9:1 mixture of LTMP and LDA: Tetrahedron Lett., 37, 6551 (1996).
  • Beilstein: 5,IV,678

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P303+P361+P353
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSDA1225000
Packing GroupIII
UN Number 1993
Hazard Codes 3 Xn,F,Xi
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class3

其他信息

  • 间溴氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010063 间溴氟苯 100g 940元 2011/04/16 B0882 3-溴氟苯 3-Bromofluorobenzene 250G 2440元 2011/04/16 B0882 3-溴氟苯 3-Bromofluorobenzene 25G 480元
  • Hazard Note:Flammable/Irritant
  • 用途一:用作医药、农药中间体
  • TCI Shanghai:1-氟-3-溴苯 3-Bromofluorobenzene,>;98.0%(GC)(1073-06-9)
  • MOL 文件:1073-06-9.mol
  • 不溶于水，和大多数有机溶剂混溶。
  • 下游产品:2,6-二甲基苯甲醛 --> 2-溴-6-氟苯甲酸
  • 检测方法:HPLC
  • 海关编码:29036990
  • Sigma Aldrich:1073-06-9(sigmaaldrich)
  • Acros Organics:3-溴氟苯 3-Bromofluorobenzene, 99%(1073-06-9)
  • MSDS 信息:1-Bromo-3-fluorobenzene(1073-06-9).msds
  • Alfa Aesar:1-溴-3-氟苯,99% 1-Bromo-3-fluorobenzene, 99%(1073-06-9)
  • 图谱信息:间溴氟苯(1073-06-9)质谱(MS) 间溴氟苯(1073-06-9)核磁图( 1 HNMR) 间溴氟苯(1073-06-9)红外图谱(IR1)
  • 用途二:医药、农药、液晶材料中间体。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C6 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C6 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C13 to C37+