Aluminium Tribromide 溴化铝

CAS 7727-15-3 MFCD00003421

化学结构图

7727-15-3
SMILES: Br[AlH3](Br)Br

化学属性

Mol. FormulaAl
Mol. Weight267
Density 3.205
Vapor Pressure1 mmHg ( 81.3 °C)
Melting Point97
TSCAYes
Boiling Point256°C(lit.)
SolubilityReacts with water violently, soluble in alcohol, carbon disulfide, ether
Flash Point268°C subl.
Appearance powder

别名和识别编码

Chemical NameAluminium Tribromide
Synonym ALUMINIUM BROMIDE HEXAHYDRATE Aluminum bromide (AlBr3) 溴化铝 溶液 Aluminum bromide, 99.99+% metals basis 溴化铝, 半干, 99.999% (METALS BASIS) aluminumbromide[albr3] aluminium tribromide Aluminiumbromid wasserfrei 溴化铝 无水溴化铝 Aluminum tribromide Aluminum bromide Aluminum bromide anhydrous AlBr3 dialuminium hexabromide 溴化铝, 99.997% (METALS BASIS) aluminumbromide,anhydrous 溴化铝,半干 aluminium (III) bromide aluminium bromide 六水合溴化铝 Aluminium tribromide Tribromoaluminum ALUMINUM BROMIDE Aluminium Bromide 三溴化铝(无水) 无水三溴化铝
CAS Number7727-15-3
EC Number231-779-7
Beilstein Registry Number2384789
MDL NumberMFCD00003421
PubChem Substance ID253660876
Merck Number332
Chemical Name Translation溴化铝
Reaxys-RN3587235
Wiswesser Line Notation.AL..E3
LabNetwork Molecule IDLN01239556
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分类

  • {SA} Al, Aluminum, Aluminum Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Lewis Acids, Materials Science, Metal and Ceramic Science, Salts, Synthetic Reagents, Ultra-High Purity Materials
  • {SNA} Acids, Acids & Bases, Al, Aluminum, Aluminum Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Essential Chemicals, Lewis Acids, Materials Science, Metal and Ceramic Science, Research Essentials,
  • {SNA} Acids, Ac

产品应用

  • 用作分析试剂、有机合成异构化的催化剂

相关文献及参考

  • Merck: 14,332
  • Short: III/20a
  • Short: III/20b
  • Short: III/31b

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R50/53
Precautionary statements
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P301+P330+P331
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSBD0350000
Packing GroupII
UN Number 1725
Storage condition Moisture Sensitive 密封充氩保存
Hazard Codes C
Hazard Class8
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1598 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHTOEH Pharmacology and Toxicology (Copenhagen).  (Munksgaard International
   Pub., POB 2148, DK-1016 Copenhagen K, Denmark)  V.60-    1987-
   Volume(issue)/page/year: 60,280,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 815 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHTOEH Pharmacology and Toxicology (Copenhagen).  (Munksgaard International
   Pub., POB 2148, DK-1016 Copenhagen K, Denmark)  V.60-    1987-
   Volume(issue)/page/year: 60,280,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1068 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHTOEH Pharmacology and Toxicology (Copenhagen).  (Munksgaard International
   Pub., POB 2148, DK-1016 Copenhagen K, Denmark)  V.60-    1987-
   Volume(issue)/page/year: 60,280,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1623 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHTOEH Pharmacology and Toxicology (Copenhagen).  (Munksgaard International
   Pub., POB 2148, DK-1016 Copenhagen K, Denmark)  V.60-    1987-
   Volume(issue)/page/year: 60,280,1987

其他信息

  • 用途四:用作分析试剂、有机合成异构化的催化剂
  • 上游原料:氢氧化铝
  • 毒性分级:中毒
  • 爆炸物危险特性:遇水可爆
  • Hazard Note:Irritant
  • 用途一:用作分析试剂、异构化的催化剂
  • 用途二:用作橡胶的热软化剂、有机合成异构化催化剂,可用于生产氢化铝锂
  • 外观性质:白色或淡黄色片状或块状固体,易潮解。
  • 灭火剂:干砂、干石粉; 禁止用水
  • 用途三:用作有机合成催化剂。溴化剂。分析试剂,异构化的催化剂。用于橡胶工业。
  • 海关编码:28275900
  • 三溴化铝价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 198410250 三溴化铝 Aluminium bromide 98+%, extra pure, anhydrous 25 GR 388元 2010/06/21 198411000 三溴化铝 Aluminium bromide 98+%, extra pure, anhydrous 100 GR 1048元 2010/05/25 89065 Aluminum bromide, 99.997% (metals basis) 5g 461元
  • 易潮解。和水反应,易溶于乙醇、乙醚、二硫化碳、苯、甲苯、硝基苯和二甲苯
  • 参考质量标准:企业标准 沪Q/HG 22-674-67 指标名称 指标(试剂级) 溴化铝含量/%≥ 95 水不溶物/%≤ 0.05 铁(Fe)/%\≤ 0.01 硫酸盐(SO4 2- )/%≤ 0.1 重金属(Pb)/%≤ 0.005 碱土金属/%≤ 0.5 酸度/%≤ 0.4
  • 类别:腐蚀物品
  • 储运特性:库房通风低温干燥; 与碱类、易燃物分开存放
  • 职业标准:TLV-TWA 2 毫克(铝)/立方米
  • 下游产品:4-硝基儿茶酚
  • 蒸气压:1 mm Hg ( 81.3 °C)
  • 可燃性危险特性:在湿气中冒烟; 遇水发热至爆炸; 受热分解有毒溴化物和氧化铝烟雾
  • 毒性:有毒性及腐蚀性。经口或吸人会中毒。与水剧烈反应释出刺激性和腐蚀性的气体,能严重刺激眼睛、黏膜、皮肤和呼吸系统。应使吸人蒸气的患者脱离污染区,安置休息并保暖。眼睛受刺激用水冲洗,皮肤接触用水冲洗;误服立即漱口,急送医院救治。操作人员必须穿戴全身耐酸防护用品。对泄漏物处理,用干砂混合,送到空旷地方,分批逐渐倒入水中经稀释的污水放入废水系统。
  • F:21
  • Sigma Aldrich:7727-15-3(sigmaaldrich)
  • Alfa Aesar:溴化铝,半干,99.999%(metalsbasis) Aluminum bromide, ultra dry, 99.999% (metals basis)(7727-15-3)
  • Acros Organics:无水溴化铝 Aluminium bromide, anhydrous, extra pure, 98+%(7727-15-3)
  • MOL 文件:7727-15-3.mol
  • 急性毒性:口服-大鼠 LD50: 1598 毫克/公斤; 口服-小鼠 LD50: 1623 毫克/公斤
  • MSDS 信息:三溴化铝(无水)(7727-15-3).msds
  • 方法一:可用金属铝或铝化合物法制造。 金属铝法将铝加入反应器中,加入溴素进行反应,生成溴化铝,经减压蒸馏制得三溴化铝,其 2A1+3Br2→2AIBr3 氢氧化铝法 将氢氧化铝加入反应器中,加氢溴酸溶解反应,生成溴化铝。其 Al(OH)3+3HBr→A1Br3+3H2O
  • 敏感性:Moisture Sensitive

系列性分类


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