Cyclohexylboronic acid 环己基硼酸

CAS 4441-56-9 MFCD01311824

化学结构图

4441-56-9
SMILES: OB(O)c1ccccc1

化学属性

Mol. FormulaC6H13BO2
Mol. Weight127.98
Melting Point122-123°C
Solubility25 g/L
Stability对热敏感,对空气敏感
Boiling Point252.4°C at 760 mmHg

别名和识别编码

Chemical NameCyclohexylboronic acid
CAS Number4441-56-9
Alfabeta NameCYCLOHEXYLBORONICACID
MDL NumberMFCD01311824
PubChem Substance ID87559608
Synonym Cyclohexylboronic acid {LY} Cyclohexylboronic acid {} {LY} Cyclohexylboronic acid {} {} {LY} Cyclohexylboronic acid {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation环己基硼酸
Reaxys-RN1921820
Beilstein Registry Number16(4)1653
InChIKeyXDRVAZAFNWDVOE-UHFFFAOYSA-N
Wiswesser Line NotationL6TJ ABQQ
LabNetwork Molecule IDLN00117614
InChIInChI=1S/C6H13BO2/c8-7(9)6-4-2-1-3-5-6/h6,8-9H,1-5H2
Canonical SMILESOB(O)C1CCCCC1
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分类

  • {SNA} Alkyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents

产品应用

  • Reactant involved in:
  • 1.HF-free synthesis of tetrabutylammonium trifluoroborates.
  • 2.Cross-coupling with aromatic amines.
  • 3.Suzuki cross-coupling reactions.
  • 4.Arylation and alkylation of diphenylisoxazole.

相关文献及参考

  • 1. G. K. Prakash, et al., , HF-free, direct synthesis of tetrabutylammonium trifluoroborates Synthesis 2 , 292-302, (2011)
  • 2. M. Larrosa, et al., , Selective copper-promoted cross-coupling of aromatic amines with alkyl boronic acids Synlett 14 , 2101-2105, (2010)
  • 3. K. C. Akula, et al., , Microwave-promoted Suzuki cross-coupling reactions of quinazoline halides with aryl boronic acids Asian J. Chem. 20 , 119-124, (2008)
  • 4. J. Chu, et al., , Palladium-Catalyzed Arylation and Alkylation of 3,5-Diphenylisoxazole with Boronic Acids via C-H Activation Organometallics 27 , 5173-5176, (2008)

安全信息

Warnings IRRITANT
WGK Germany3
RTECSGU7171000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xi
Safety Statements
Storage condition -20°C {LY} -20°C 0-10°C Refrigerator (+4°C) {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Signal word
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02141

其他信息

  • 环己基硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C2188 环己基硼酸(含有数量不等的酸酐) Cyclohexylboronic Acid (contains varying amounts of Anhydride) 5G 1460元 2014/06/02 C2188 环己基硼酸(含有数量不等的酸酐) Cyclohexylboronic Acid (contains varying amounts of Anhydride) 1G 474元 2010/06/21 359050010 环己基硼酸 Cyclohexylboronic acid 97% 1 GR 129元
  • TCI Shanghai:环己基硼酸(含有数量不等的酸酐) Cyclohexylboronic Acid (contains varying amounts of Anhydride)(4441-56-9)
  • Sigma Aldrich:4441-56-9(sigmaaldrich)
  • Acros Organics:环己基硼酸 Cyclohexylboronic acid, 97%(4441-56-9)
  • MOL 文件:4441-56-9.mol

系列性分类


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