1-Hexanethiol 1-己硫醇

CAS 111-31-9 MFCD00004909

化学结构图

111-31-9
SMILES: CCCCCCS

化学属性

Mol. FormulaC6H14S
Mol. Weight118
Refractive index1.4480 to 1.4520
Boiling Point150-154
Density0.838
Melting Point-81 - -80
Flash Point30°C(lit.)
TSCAYes
Solubility不溶于水，易溶于醇、醚。
Stability对空气敏感

别名和识别编码

Chemical Name1-Hexanethiol
Synonym hexanethiolnormal n-thioheptylalcohol HEXYL MERCAPTAN 己硫醇 硫代己醇 1-Mercaptohexane Hexyl mercaptan MCH Mercaptan C6 Mercaptan C6 巯基己烷 hexylmercaptannormal hexylmercaptan(non-specificname) hexyl mercaptan hexyl hydrosulfide 1-hexanethiol N-HEXYL MERCAPTAN hexane-1-thiol Hexanethiol MERCAPTAN C6 1-Mercaptohexane 1-巯基己烷 MCH n-Hexylthiol 己硫醇;巯基己烷 Hexyl mercaptan 1-琉基乙烷 1-Hexanthiol 1-Hexyl mercaptan 1-Hexylthiol n-Hexanethiol 1-MERCAPTOHEXANE hexanethiol(non-specificname) hexan-1-thiol Hexylmercaptan 1-己硫醇 Hexan-1-thiol 1-hexylthiol 1-HEXANETHIOL FEMA 3842 1-己烷硫醇 hexylthiol USAF EK-4628 1-HEXYLMERCAPTAN Hexylthiol n-Hexyl mercaptan
CAS Number111-31-9
PubChem Substance ID87570549
EC Number203-857-0
Beilstein Registry Number1731295
MDL NumberMFCD00004909
Reaxys-RN1731295
Chemical Name Translation1-己硫醇
Wiswesser Line NotationSH6
LabNetwork Molecule IDLN00162980
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分类

  • Alkyl Thiols, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols
  • {Chemicalbook} 食品添加剂: 食用香料（增香剂）: 天然等同香料和人造香
  • {SNA} Alkyl Thiols, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols, 材料科学
  • {SNA} Alkyl Thiols, Micro/NanoElectronics, Self Assembly and Lithography, Self-Assembly Materials, Thiols, 材料科学
  • {SNA} Alkyl Thiols, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols
  • {uni_hamburg} no charge; thiol; 1fragment

产品应用

  • 用于调节网络碳纳米管场效应晶体管的电特性。还用作铜表面的单分子层，以在铜暴露于环境中时延迟其?表面氧化，之后可通过在惰性 N2 中的退火步骤得到有效解吸，从而提供清洁的铜表面。

相关文献及参考

  • Short: IV/18B
  • Beilstein:1,408
  • Short: IV/16
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H331 Toxic if inhaled 吸入中毒
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 Xn
RTECSMO4550000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P304+P340+P311
  • P305+P351+P338
  • P308+P311
  • P309+P311
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P370+P378
  • P403+P233
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R10 Flammable 易燃
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 1228 UN 1228 3/PG 2 UN3071
Storage condition Flammables area 对空气敏感，密闭充氩保存。 Air Sensitive
Packing GroupIII
Hazard Class3/6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1080 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - respiratory stimulation
   Behavioral - somnolence (general depressed activity)
   Sense Organs and Special Senses (Eye) - lacrimation
REFERENCE

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1254 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
   Behavioral - coma
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,171,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 396 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,171,1958

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUT

Restrict 危险品

其他信息

  • Acros Organics:1-己烷硫醇 1-Hexanethiol, 96%(111-31-9)
  • Alfa Aesar:1-己硫醇,97% 1-Hexanethiol, 97%(111-31-9)
  • 毒性:GRAS(FEMA)。
  • 可燃性危险特性:明火可燃; 遇热放出有毒氧化硫气体
  • 储运特性:库房通风低温干燥; 与食品、酸类、氧化剂分开储运
  • 使用限量:FEMA(mg/kg)：焙烤制品、无醇饮料、早餐谷物、冷饮、调味汁、肉制品、乳制品、软糖、汤品、甜沙司，均0.1～5.0；调味香料0.5～5.0。
  • MSDS 信息:己硫醇(111-31-9).msds
  • 灭火剂:泡沫、干粉、二氧化碳
  • TCI Shanghai:己硫醇 Hexyl Mercaptan,>;96.0%(GC)(111-31-9)
  • 图谱信息:1-己硫醇(111-31-9)质谱(MS) 1-己硫醇(111-31-9)核磁图( 1 HNMR) 1-己硫醇(111-31-9)核磁图( 13 CNMR) 1-己硫醇(111-31-9)红外图谱(IR1)
  • 类别:有毒物品
  • 上游原料:氢氧化钠 --> 乙醚 --> 氢溴酸 --> 硫脲 --> 正己醇
  • 职业标准:AIR CL 0.5 PPM/15 M
  • MOL 文件:111-31-9.mol
  • FEMA:3842
  • 1-己硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0103 己硫醇 Hexyl Mercaptan 25ML 307元 2014/06/02 H0103 己硫醇 Hexyl Mercaptan 500ML 1960元 2010/06/21 215275000 1-己硫醇 1-Hexanethiol 96% 500 ML 1876元
  • 检测方法:GC
  • F:13
  • 存储注意事项:空气敏感;氮气保护
  • Sigma Aldrich:111-31-9(sigmaaldrich)
  • 急性毒性:口服- 大鼠 LD50: 1254 毫克/ 公斤; 腹腔- 小鼠 LD50: 200 毫克/ 公斤
  • 毒性分级:高毒
  • 敏感性:Air Sensitive
  • 外观性质:无色液体，有恶臭。
  • 不溶于水，溶于醇、乙醚和烃。
  • 用途一:食品用香料。
  • 参考质量标准:FAO/WHO，1999 含量(GT-10-4) ≥95% 相对密度(d 25 25 ) 0.824～0.835

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly & Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly & Contact Printing
  5. Thiols - Self-Assembly Materials
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly & Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly & Contact Printing
  5. Thiols - Self-Assembly Materials
  6. Alkyl Thiols - Thiols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol/Mercaptan Salts
  1. Functional Group 官能团索引
  2. alkylthiol

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